Safety Data Sheets (SDSs) are the primary document for communicating hazard and safe handling information through the supply chain. In GB, SDS requirements are set by UK REACH (retained EU REACH Regulation (EC) No 1907/2006, Article 31 and Annex II), with classification information drawn from GB CLP.
The SDS must be compiled in accordance with the version of Annex II that was in force on 31 December 2020 (the UK did not adopt the EU's 2020 update to Annex II, Commission Regulation (EU) 2020/878, which only applies in the EU and Northern Ireland).
- Legal basis
- UK REACH Article 31 and Annex II (retained EU REACH Regulation 1907/2006 as amended for GB)
- Language requirement
- English (mandatory for SDSs supplied in Great Britain)
- Format
- 16 mandatory sections in the prescribed order; sections must not be left blank
- GB Annex II version
- Version in force on 31 December 2020. The EU 2020/878 update does NOT apply in GB.
- Responsible authority
- Defra (Department for Environment, Food and Rural Affairs) has lead policy responsibility for SDS requirements in GB
- Enforcement
- HSE and local authorities enforce SDS requirements under the REACH Enforcement Regulations 2008
When an SDS must be provided
Under UK REACH Article 31, an SDS must be provided to the recipient when:
- A substance or mixture is classified as hazardous under GB CLP
- A substance is persistent, bioaccumulative and toxic (PBT) or very persistent and very bioaccumulative (vPvB) under UK REACH Annex XIII criteria
- A substance is on the UK REACH Candidate List (substances of very high concern, SVHCs)
An SDS must be provided on request where a mixture is not classified as hazardous but contains:
- A substance posing health or environmental risk at 1% or more by weight (non-gaseous mixtures) or 0.2% or more by volume (gaseous mixtures)
- A PBT, vPvB or Candidate List substance at 0.1% or more by weight
- A substance with a GB workplace exposure limit
- SDS for classified substances/mixtures
- Mandatory - must be provided no later than first supply
- SDS for PBT/vPvB substances
- Mandatory - must be provided no later than first supply
- SDS for Candidate List substances
- Mandatory - must be provided no later than first supply
- SDS on request - health/environmental substance threshold
- 1% or more by weight (non-gaseous) or 0.2% or more by volume (gaseous)
- SDS on request - PBT/vPvB/SVHC substance threshold
- 0.1% or more by weight
- SDS on request - workplace exposure limit
- Must be provided on request if mixture contains substance with a GB workplace exposure limit
- General public exemption
- SDS need not be supplied where hazardous substances or mixtures sold to general public are provided with sufficient safety information, unless requested
16-section SDS format (UK REACH Annex II)
Every SDS must contain all 16 sections in the following prescribed order. No sections may be omitted, though individual subsections may state that information is not applicable or not available (with justification).
- Section 1
- Identification of the substance/mixture and of the company/undertaking - product identifier, relevant uses, supplier details, emergency telephone number
- Section 2
- Hazards identification - GB CLP classification, label elements (pictograms, signal word, H-statements, P-statements), other hazards (PBT/vPvB assessment)
- Section 3
- Composition/information on ingredients - chemical identity, impurities, concentration ranges of hazardous components
- Section 4
- First-aid measures - description of measures by route of exposure, important symptoms, indication of medical attention needed
- Section 5
- Firefighting measures - suitable extinguishing media, specific hazards from the chemical, advice for firefighters
- Section 6
- Accidental release measures - personal precautions, environmental precautions, containment and cleanup methods
- Section 7
- Handling and storage - precautions for safe handling, conditions for safe storage including incompatibilities, specific end uses
- Section 8
- Exposure controls/personal protection - GB workplace exposure limits (WELs), engineering controls, PPE requirements
- Section 9
- Physical and chemical properties - appearance, odour, pH, melting/boiling point, flash point, flammability, vapour pressure, density, solubility
- Section 10
- Stability and reactivity - reactivity hazards, chemical stability, conditions to avoid, incompatible materials, hazardous decomposition products
- Section 11
- Toxicological information - likely routes of exposure, symptoms related to physical/chemical/toxicological characteristics, numerical toxicity measures
- Section 12
- Ecological information - toxicity to aquatic organisms, persistence and degradability, bioaccumulative potential, mobility in soil
- Section 13
- Disposal considerations - waste treatment methods, relevant disposal legislation
- Section 14
- Transport information - UN number, proper shipping name, transport hazard class, packing group, environmental hazards, special precautions
- Section 15
- Regulatory information - GB safety, health and environmental regulations specific to the substance or mixture
- Section 16
- Other information - revision date, version number, changes from previous version, abbreviations, key literature references
Delivery and update obligations
The SDS must be provided free of charge, on paper or electronically, no later than the date on which the substance or mixture is first supplied to the recipient.
- Delivery timing
- No later than the date of first supply to the recipient
- Delivery format
- Paper or electronic (e.g. email, PDF download), free of charge
- Update obligation
- Supplier must update the SDS without delay when new information affecting risk management becomes available, or when a new hazard is identified, or when an authorisation is granted or refused, or when a restriction is imposed
- Update distribution
- Updated SDS must be provided to all recipients who received the substance or mixture within the preceding 12 months
- Revision tracking
- Updated SDS must be dated, marked as revision, and changes identified in Section 16
- Exposure scenarios
- Where a chemical safety assessment has been carried out, relevant exposure scenarios must be annexed to the SDS (extended SDS)
Enforcement and penalties
SDS requirements are enforced under the REACH Enforcement Regulations 2008. Failure to provide an SDS, or providing an SDS that does not comply with Annex II requirements, is a criminal offence.
- Enforcement legislation
- REACH Enforcement Regulations 2008 (SI 2008/2852)
- Summary conviction penalty
- Fine not exceeding the statutory maximum and/or imprisonment up to 3 months
- Conviction on indictment penalty
- Unlimited fine and/or imprisonment up to 2 years
- Enforcing authority
- HSE and local authorities